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In many cases the best performance occurs when most of the crosslinking happens after the product is applied to the paper.
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But our preference is to have the polymer mostly crosslink after application to a substrate.
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In polymer chemistry cross linking usually refers to the use of cross links to promote a change in the polymers physical properties.
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In chemistry and biology a cross link is a bond that links one polymer chain to another.
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Using paper as an example again the polymer would be applied to the paper and fused together after application.
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These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural polymers such as proteins.